Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 29, Pages 4583-4586Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201000837
Keywords
Ligand design; Polytopic ligands; Self-assembly; Grid structure; Supramolecular chemistry; Manganese; Copper
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Funding
- Canadian Natural Sciences and Engineering Research Council (NSERC) [1031-07]
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The tetratopic pyridazine-hydrazone ligand L2 is based on a design that successfully produces self-assembled [4 x 4] M-16(II) (M = Mn, Cu) grids, but incorporates pi-charge-rich, strong field bipy end groups. L2 forms an unusual incomplete super triangular Cu-11(II) motif, dominated by the bipy ends. We now describe the incomplete M-12(II) partial grid [Mn-12(L2-2H)(6)(L-H)(2){N(CN)(2)}(2)].
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