Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 4, Pages 471-474Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201001156
Keywords
Metal-organic frameworks; Mesoporous materials; Adsorption; Adsorption chilling; Heat transformation
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Funding
- Federal German Ministry of Economics (BMWi) [0327851]
- Deutsche Forschungsgemeinschaft (DFG) [Ja466/14-1]
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The adsorption of water vapor in the highly porous metal-organic framework (MOF) of 3D-[Cr3F(H2O)(2)O(bdc)(3)center dot similar to 25H(2)O] (MIL-101) (bdc = benzene-1,4-dicarboxylate, terephthalate) of up to 1 g of water per gram of sorbent material (between 140 degrees C and 40 degrees C under a water vapor pressure of 5.6 kPa) together with the stability over several cycles makes MIL-101 the most promising material, so far, for heat transformation applications like thermally driven heat pumps or adsorption chillers.
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