Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 4, Pages 581-588Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201000918
Keywords
Silicon; Cyanides; Phosphanes; Iron; Sulfur; Hydrogenase
Categories
Funding
- Studienstiftung des Deutschen Volkes
- Science Foundation Ireland [06/CHPRFP/029]
Ask authors/readers for more resources
Cyanido- and phosphane-substituted [FeFe] hydrogenase models are known to show increased basicity of the [2Fe2S] cluster. Following our continued interest in [2Fe2S(Si)] compounds, substitution reactions of such complexes with tetraethylammonium cyanide as well as triphenylphosphane were investigated to yield the respective monosubstituted triphenylphosphane complexes 2a-c and cyanido complexes 3a-c. Cyclic voltammetry was used to investigate the electrocatalytic H-2 formation with acetic acid.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
