Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 5, Pages 675-679Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200901183
Keywords
Amphiphiles; Spin crossover; Iron; Molecular switching; Magnetic properties
Categories
Funding
- Irish Research Council for Science
- Engineering and Technology
- Swiss National Science Foundation
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Thermal spin crossover (SCO) was induced in a high-spin Fe-III complex by alkylation of the polyamino ligand backbone. The SCO profile was responsive to chain length with partial crossover observed with C-6 alkylation and full transition upon lengthening to C-12. No crossover was observed when the backbone was unfunctionalised, and all three complexes were obtained as unsolvated tetrafluoroborate salts.
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