Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 16, Pages 2338-2343Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200801224
Keywords
Microporous materials; Coordination polymers; Crystal engineering; Magnetic properties; Carboxylate ligands; Metal-organic frameworks
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Funding
- Institute for Paper Science and Technology at the Georgia Institute of Technology
- Department of Energy [DE-FG-02-03-ER 46035]
- European Union Marie Curie International Reintegration [036577]
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In this paper, we report on a high-throughput (gram quantities) solvothermal method for the synthesis of copper terephthalate metal-organic frameworks in dmf. While the structure of MOF-2 and some of the associated polymorphs are well known, we know of no equivalent structural studies for the isostructural copper terephthalate (Cu-tpa). The material we have made crystallizes in the C2/m space group. Cu-tpa also exhibits reversible solvent-exchange properties. These properties make this material useful for potential applications in gas storage and catalysis applications. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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