Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 13, Pages 1723-1728Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200801207
Keywords
Heck reaction; Carbene ligands; Palladium; Self-assembly; NHCs (N-Heterocyclic carbenes)
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Funding
- Sharighai Municipal Committee of Science and Technology [06XD14005, 08dj1400100-2]
- National Basic Research Program of China [(973)-2009CB825300]
- National Natural Science Foundation of China [20872162, 20672127, 20732008, 20702013]
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A new family of imidazole-coordinated monodentate NHC-metal complexes 9 was obtained as well as cis-chelated bidentate NHC-metal complexes 10 from novel bis(imidazolium) salts 4 with a biphenyl backbone. The structures of complexes 9a and 10b were determined by X-ray crystal-structure diffraction, and their application in the Heck reaction showed good to excellent catalytic activities under very mild conditions. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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