Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 28, Pages 4288-4297Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200900447
Keywords
Palladium; N,S ligands; Nitrogen heterocycles; Cross-coupling; Carbene ligands
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Funding
- National University of Singapore (NUS)
- Ministry of Education & Agency for Science, Technology Research [R-143-000-277-305, 8143-000-361-112]
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A series of mixed-ligand, mononuclear complexes trans[PdX2(NSHC)(azole)] [NSHC = N,S-heterocyclic carbene; azole = imidazole, 1-(2,4,6-trimethylphenyl)-1H-imidazole, benzimidazole, benzothiazole and benzoxazole] have been prepared and characterised by X-ray single-crystal diffraction. These complexes catalyse the sp(2)-sp(3) cross-coupling of fluoroaryl halides with arylboronic acid to give diarylmethanes with good yields and high turnovers. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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