Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 34, Pages 5071-5074Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200900638
Keywords
Cluster compounds; Molybdenum; Iron; Vanadium; Polyoxometalates; Metal-metal interactions; Molecular magnetism
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Funding
- RWTH Aachen University for a Seed Fund
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The formation of a self-assembled multi-heterometal Keplerate polyoxomolybdate demonstrates compositional control of linker groups in spherical clusters. The resulting partially reduced {Mo(72)(V/VI)Fe(20)(III)V(8)(IV)Mo(2)(V)}-type cluster exhibits intramolecular ferrimagnetic ordering characteristic of such mixed-spin Keplerate systems. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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