Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 17, Pages 2659-2663Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200800153
Keywords
hydroformylation; supercritical carbon dioxide; rhodium; cyclodextrins; P ligands
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The presence of peracetylated beta-cyclodextrin in the reaction medium allowed for an increase in the solubility of rhodium species modified by alkyl P-donor ligands in the catalytic hydroformylation of 1-octene in supercritical carbon dioxide. These results were explained by considering an interaction between the peracetylated P-cyclodextrin and the P-donor ligands. (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008.
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