4.5 Review

Chirality in Polyoxometalate Chemistry

Journal

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 32, Pages 5001-5013

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200800759

Keywords

Polyoxometalates; Chiral resolution; Organic-inorganic hybrid composites; Molecular recognition; Anions

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The increasing use of polyoxometalates in the fields of material sciences, catalysis, and biology has raised the interest in chirality of such systems. This review provides a summary of the different strategies followed: i) chirality in solid-state arrangements, H) chiral polyoxometalate frameworks, and iii) chiral polyoxometalate-organic hybrids. Through the discussion of selected examples, an outline for future work is drawn. (c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)

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