4.5 Article

Photoinduced ligand transformation in a ruthenium polypyridophenazine complex

Journal

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 7, Pages 1031-1034

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200700947

Keywords

ruthenium compounds; nitrogen heterocycles; photooxidation; photochemistry

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Irradiation of a ruthenium polypyridyl complex in the presence of oxygen leads to the oxidation of a benzodipyrido-phenazine ligand to a quinone. The corresponding tetraaza-tetrapyridopentacene complex is not oxidized under the same conditions. (c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).

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