Journal
JOURNAL OF SURFACE INVESTIGATION
Volume 9, Issue 1, Pages 17-23Publisher
PLEIADES PUBLISHING INC
DOI: 10.1134/S1027451015010176
Keywords
barium hexaferrites; neutron diffraction; crystalline and magnetic structure
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The structural study of barium hexaferrite (BaFe12O19) whose iron ions are partly replaced by diamagnetic aluminum ions (x = 0.6) is carried out with the help of the neutron-diffraction method. Experimental data are acquired in a wide temperature range of 4- 730 K via a high-resolution diffractometer, which makes it possible to obtain both precise information on changes in crystalline and magnetic structures and behavioral data on the sample microstructure. BaFe11.4Al0.6O19 retains the magnetoplumbite structure in the whole temperature range and exhibits the invar effect,according to which its bulk thermal-expansion coefficient is close to zero at low temperatures (<150 K). The magnetic structure is defined by the Gorter model with magnetic moments oriented along the hexagonal axis. For all nonequivalent crystallographic positions, the magnetic moment of F3+ is close to 4 mu B at 4 K. The total magnetic moment per formula unit is 15.6 mu B, i.e., less than the nominal value of 20 mu B. This is caused by the fact that diamagnetic Alions are included in the composition. Crystallite microstrains increase insignificantly with temperature due to increasing influence of the magnetic subsystem.
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