4.4 Article

Antinematic local order in dendrimer liquids

Journal

EPL
Volume 106, Issue 4, Pages -

Publisher

IOP PUBLISHING LTD
DOI: 10.1209/0295-5075/106/44004

Keywords

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Funding

  1. Marie-Curie Initial Training Network COMPLOIDS [234810]
  2. Slovenian Research Agency [P1-0055]
  3. Austrian Science Fund (FWF) [P23910-N16, F41]

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We use monomer-resolved numerical simulations to study the positional and orientational structure of a dense dendrimer solution, focusing on the effects of the prolate shape and deformability of the dendrimers on the short-range order. Our results provide unambiguous evidence that the nearest-neighbor shell of a tagged particle consists of a mixture of crossed, side-by-side, side-to-end, and end-to-end pair configurations, imposing antinematic rather than nematic order observed in undeformable rodlike particles. This packing pattern persists even at densities where particle overlap becomes sizable. We demonstrate that the antinematic arrangement is compatible with the A15 crystal lattice reported in several dendrimer compounds. Copyright (C) EPLA, 2014

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