Journal
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
Volume 17, Issue 5, Pages 1063-1069Publisher
SPRINGER HEIDELBERG
DOI: 10.1007/s11356-009-0260-z
Keywords
Pesticide by-products; Aromatic nitroderivatives; Photochemistry; Shallow surface waters
Categories
Funding
- Universita di Torino-Ricerca Locale
- Italian University Consortium of Chemistry and the Environment (INCA)
- Marie Curie International Incoming Fellowship (IIF) [PIIF-GA-2008-219350]
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Background, aim and scope Photochemical processes can decontaminate the aqueous environment from xenobiotics, but they also produce secondary pollutants. This paper presents field and laboratory evidence of the transformation of 4-chlorophenol (4CP) into 2-nitro-4-chlorophenol (2N4CP). Materials and methods Field monitoring of 4CP and 2N4CP was carried out by solid phase extraction coupled with liquid chromatography-multiple reaction monitoring mass spectrometry. Laboratory irradiation experiments were carried out under a UV-Vis lamp, and the time evolution of the compounds of interest was followed by liquid chromatography. Purpose The purpose of this study was elucidating the pathways leading to 2N4CP from 4CP in paddy field water. Results and discussion The field monitoring results suggest that 4CP can be transformed into 2N4CP in the paddy field water of the Rh ne delta (Southern France). The laboratory study indicates that the transformation can take place via photonitration by (NO2)-N-center dot. The nitration process is inhibited by bicarbonate, possibly due to basification that favours the occurrence of the 4-chlorophenolate. The latter could consume (NO2)-N-center dot without being nitrated. Photonitration in the presence of bicarbonate could account for the observed transformation in the field. Conclusions Photonitration of 4CP to 2N4CP by (NO2)-N-center dot could account for the observed interconversion of the two compounds in paddy fields. The results are of concern because 2N4CP is biorecalcitrant and toxic. Recommendations and perspectives Bicarbonate can modulate the photonitration of 4CP into 2N4CP, which can be very significant in bicarbonate-poor waters.
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