Journal
ENVIRONMENTAL SCIENCE & TECHNOLOGY
Volume 46, Issue 21, Pages 12203-12208Publisher
AMER CHEMICAL SOC
DOI: 10.1021/es302169c
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Funding
- Dutch Ministry of Economic Affairs
- European Union
- Province of Friesland
- City of Leeuwarden
- EZ/Kompas program of the Samenwerkingsverband Noord-Nederland
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Energy extraction based on capacitive Donnan potential (CDP) is a recently suggested technique for sustainable power generation. CDP combines the use of ion-exchange membranes and porous carbon electrodes to convert the Gibbs free energy of mixing sea and river water into electric work. The electrodes geometry has a relevant impact on internal resistance and overall performance in CDP. In this work, we present the first effort to use wire shaped electrodes and its suitability for improving CDP. Analytical evaluation and electrical measurements confirm a strong nonlinear decrease in internal resistance for distances between electrodes smaller than 3 mm. We also demonstrated that we get more power per material invested when compared to traditional flat plate designs. These findings show the advantages of this design for further development of CDP into a mature technology.
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