4.8 Article

Estimation of Liquid Fuel Yields from Biomass

Journal

ENVIRONMENTAL SCIENCE & TECHNOLOGY
Volume 44, Issue 13, Pages 5298-5305

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/es100316z

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Funding

  1. US Department of Energy [DE-FG 3608GO18087]
  2. AFOSR [FA 9550-08-1-0456]

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We have estimated sun-to-fuel yields for the cases when dedicated fuel crops are grown and harvested to produce liquid fuel. The stand-alone biomass to liquid fuel processes, that use biomass as the main source of energy, are estimated to produce one-and-one-half to three times less sun-to-fuel yield than the augmented processes. In an augmented process, solar energy from a fraction of the available land area is used to produce other forms of energy such as H-2, heat etc., which are then used to increase biomass carbon recovery in the conversion process. However, even at the highest biomass growth rate of 6.25 kg/m(2).y considered in this study, the much improved augmented processes are estimated to have sun-to-fuel yield of about 2%. We also propose a novel standalone H(2)Bioil-B process, where a portion of the biomass is gasified to provide H-2 for the fast-hydropyrolysis/hydrodeoxygenation of the remaining biomass. This process is estimated to be able to produce 125-146 ethanol gallon equivalents (ege)/ton of biomass of high energy density oil but needs experimental development The augmented version of fast-hydropyrolysis/hydrodeoxygenation, where H-2 is generated from a nonbiomass energy source, is estimated to provide liquid fuel yields as high as 215 ege/ton of biomass. These estimated yields provide reasonable targets for the development of efficient biomass conversion processes to provide liquid fuel for a sustainable transport sector.

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