4.5 Article

Identification of individual isotopes in a polymer blend using tip enhanced Raman spectroscopy

Journal

JOURNAL OF RAMAN SPECTROSCOPY
Volume 46, Issue 5, Pages 447-450

Publisher

WILEY-BLACKWELL
DOI: 10.1002/jrs.4671

Keywords

tip enhanced Raman spectroscopy; protected plasmonics; isotopic identification; polymer blend; chemical sensing

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Funding

  1. U.S. Army Research Laboratory
  2. U.S. Army Research Office [W911NF-09-1-0424]
  3. DURIP [W911NF-10-1-3167]

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For the first time, tip enhanced Raman spectroscopy (TERS) blinking measurements are used to identify the individual isotopes of non-Raman resonant polystyrene in a miscible, binary blend. This demonstrates the sensitivity and selectivity required for nanoscale chemical imaging and broadens the types of surface components potentially identifiable with TERS. Copyright (c) 2015 John Wiley & Sons, Ltd.

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