Biocidal and anti-corrosive activities of benzoimidazol-3-ium cationic Schiff base surfactants

Two series of cationic Schiff base surfactants, namely, 2-(benzylideneamino)-3-(2-oxo-2-alkoxyethyl)-1,3-benzoimidazol-3-ium bromide (IA-D) and 2-[(4-methoxybenzylidene) amino]-3-(2-oxo-2-alkoxyethyl)-1,3-benzoimidazol-3-ium bromide (IIA-D) were prepared. The chemical structures of the prepared Schiff bases were recognized by elemental analysis, FTIR, H NMR, C-13-NMR and GC/MS spectra. The surface activities of the synthesized Schiff base cationic surfactants showed their tendency towards adsorption at the air/water interface. The adsorption tendency was estimated from the values of surface tension and the depression of surface tension at the critical micelle concentration. The studied surfactants were evaluated as antimicrobial agents against pathogenic and sulfur-reducing bacteria using inhibition zone diameters and minimum inhibition concentration values. The synthesized cationic benzoimidazolium Schiff base cationic surfactants showed good antimicrobial activities against the tested microorganisms including Gram positive, Gram negative as well as fungi. The synthesized compounds were tested for the activity as corrosion inhibitors against carbon steel corrosion in 0.5M HCl at 200 and 400 ppm. The promising inhibition efficiency of these compounds against the sulfur-reducing bacteria facilitates them to be applicable in the petroleum field as new categories of Sulfur Reducing Bacteria biocides. The inhibition efficiencies of the tested compounds showed good inhibition and protection of the carbon steel. The corrosion inhibition tendency correlated to the surface activity and chemical structure of the compounds.