Rapid, ambient temperature hydrogen generation from the solid state Li-B-Fe-H system by mechano-chemical activation synthesis

A novel processing method promoting a rapid hydrogen generation from the solid state Li-B-Fe-H system is presented. The Li-B-Fe-H system is quite remarkable since the mechanical dehydrogenation rate at the ambient temperature is much higher than the thermal dehydrogenation rate at the 100 -250 degrees C range. The quantity of 4.02 wt.% H-2 is desorbed after barely 0.5 h of ball milling with a very low energy input of 36.4 kJ/g while at 250 degrees C, after the same desorption time, only 3.2 wt.% H-2 is desorbed. Thus this system is a rapid, solid state H-2 generator at the ambient temperature. X-ray diffraction after ball milling shows the presence of the crystalline LiCl diffraction peaks. The Fourier transform infrared spectroscopy (FT-IR) measurements show a spectrum characteristic of the disordered Fe(BH4)(2) hydride. Samples milled under varying energy inputs are attracted to a permanent magnet. It is shown that the thermal dehydrogenation behavior of the pre-milled samples is initially fast but then quickly slows down. The pre-milled samples after thermal dehydrogenation are also attracted to a permanent magnet. Diffraction peaks of alpha-Fe are clearly observed after thermal desorption of powders at 100 and 250 degrees C. For the sample dehydrogenated at 250 degrees C the crystallite size of the alpha-Fe phase, estimated from its diffraction peak breadths, is within a nanometric range of 27-47 nm. (C) 2015 Elsevier B.V. All rights reserved.