4.8 Article

Asymmetric supercapacitor based on nanostructured graphene foam/polyvinyl alcohol/formaldehyde and activated carbon electrodes

Journal

JOURNAL OF POWER SOURCES
Volume 273, Issue -, Pages 305-311

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2014.09.094

Keywords

Graphene foam; Polyvinyl alcohol; Formaldehyde; KOH activation; Asymmetric supercapacitor

Funding

  1. South African Research Chairs Initiative (SARChi) in carbon Technology and Matarials of the Department of Science and Technology (DST)
  2. National Research Foundation (NRF)
  3. University of Pretoria
  4. NRF

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We present the electrochemical results of highly porous and interconnected carbon material by activation of graphene foam/polyvinyl alcohol-formaldehyde composite material designated as GF/PVA-F. Asymmetric supercapacitor devices were fabricated using the activated material (GF/PVA-F) and activated carbon (AC) as the positive and negative electrodes respectively. The device exhibited a maximum energy density of 42 mWh cm(-2), a power density of 0.5 W cm(-2) and 98% retention of its initial capacitance after 2000 cycles in an extended cell potential window of 1.8 V in 1 M Na2SO4 aqueous electrolyte. This work shows the great potential of this material for high performance energy storage application. (C) 2014 Elsevier B.V. All rights reserved.

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