Journal
JOURNAL OF POWER SOURCES
Volume 273, Issue -, Pages 848-856Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2014.09.176
Keywords
SnO2@SnS2 core-shell heterojunction; Sulfurization; Interface; Diffusion; Quantum dot sensitized solar cells
Funding
- National Natural Science Foundation of China [51272080, 51072062, 51172091]
- National Basic Research Program of China [2013CB632500]
- Research Fund for the Doctoral Program of Higher Education, Ministry of Education of China [20100142110016]
- Open Fund of State Key Laboratory of Advanced Technology for Materials Synthesis and Processing
- Wuhan University of Technology [2013-KF-3]
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High-quality SnO2@SnS2 core-shell heterojunctions have been constructed through sulfurization of SnO2 nanoflowers self-sacrificial templates with H2S gas at relatively low temperature in this paper. The unreacted SnO2 core and the in-situ synthesized SnS2 shell are in good crystallinity with a low lattice mismatch interface. The formation mechanism of the core-shell heterostructures have been examined by experiments and theoretic computation from the perspectives of both adsorption and diffusion. When used as photoanode in all-solid-state semiconductor-sensitized solar cells, the SnO2@SnS2 core-shell heterojunctions based hybrid solar cell shows a promising conversion efficiency of 1.45% under 1 sun illumination, which is over 5 times than that of SnS2 quantum dot sensitized SnO2 electrode made by the common chemistry bath deposition method. The enhanced photovoltaic performance is contributed to the unique structure of SnO2@SnS2 core-shell heterojunctions which provide highly covered sensitizers and favored interface for suppressing the charge recombination from SnO2 to electrolyte. This strategy and understanding can be extended to other nanostructure core-shell architecture and fields. (C) 2014 Elsevier B.V. All rights reserved.
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