4.8 Article

MnO2@KCu7S4 NWs hybrid compositions for high-power all-solid-state supercapacitor

Journal

JOURNAL OF POWER SOURCES
Volume 274, Issue -, Pages 477-482

Publisher

ELSEVIER
DOI: 10.1016/j.jpowsour.2014.10.075

Keywords

Hybrid composite; MnO2@KCu7S4; High-power; Supercapacitors

Funding

  1. NSFC [11204388]
  2. SRFDP [20120191120039, 20110191110034]
  3. Fundamental Research Funds for the Central Universities [CQDXWL-2014-001, CDJZR12225501, CQDXWL-2013-012]
  4. Chongqing University

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Here we present a high-power all-solid-state supercapacitor based on a novel structure of MnO2@KCu7S4 NWs. The electrodes exhibit excellent electrochemical performance with large specific capacitance of 533 F g(-1) and the maximum power density 2.02 kW kg(-1), still hold 85% of the capacitance over 6000 cycles. Besides, we also explored the effect of temperature on the capacitance. When compared with capacitance at different temperatures, the specific capacity at 80 degrees C demonstrates significantly higher. Moreover, two supercapacitors in series can power 41 light-emitting diodes (LEDs) about 4 min. These results suggest that such MnO2@KCu7S4 hybrid composite is promising for next generation highperformance supercapacitors. (C) 2014 Elsevier B.V. All rights reserved.

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