4.7 Article

Alternative Solid Fuel Production from Paper Sludge Employing Hydrothermal Treatment

Journal

ENERGY & FUELS
Volume 28, Issue 2, Pages 1198-1206

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ef402371h

Keywords

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Funding

  1. Siam Cement Public Company Limited (SCG)
  2. Faculty of Engineering, Kasetsart University, Thailand
  3. State Scholarship Fund of China [2011609050]

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This paper aims to investigate the alternative solid fuel production from paper sludge employing hydrothermal treatment (HTT) in a lab-scale facility for implementation of the pilot-scale plant. The paper sludge was subjected to the HTT under subcritical hydrothermal conditions. In the lab-scale experiment, the temperature conditions were 180 degrees C, 200 degrees C, 220 degrees C, and 240 degrees C, respectively, while it was 197 degrees C in the pilot plant as the optimum condition. The holding time was 30 min in both cases. The hydrothermally produced solid fuel was evaluated for the fuel property, the water removal performance, and the mass distribution. Furthermore, the energy balance of the process was studied. The higher heating value of the HT pretreated paper sludge was slightly improved. In addition, the produced solid fuel had comparable H/C and O/C atomic ratios with that of coal, indicating the presence of carbonization during the HTT process. Using the mechanical dewatering, only 4.1% of moisture in the raw paper sludge can be removed while the solid fuel production from paper sludge by HTT at 200 degrees C showed 19.5% moisture reduction. According to the energy balance of the pilot plant, the recovered energy was significantly higher than the energy input, showing the feasibility of employing the HTT to produce alternative solid fuel from paper sludge.

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