Journal
ENERGY & FUELS
Volume 28, Issue 10, Pages 6677-6682Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ef501675m
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Funding
- National Key Technology Research and Development Program [2012BAF03B02]
- National Natural Science Foundation of China (NSFC) [21373005, 21271095, 21471073]
- Science and Technology Bureau of Liaoning Province [201202084]
- Education Bureau of Liaoning Province [LR2012001]
- Shenyang Science and Technology Program [F12-265-4-00]
- Liaoning Provincial Department of Education Innovation Team Project [LT2012001]
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A Bronsted acid ionic liquid (IL), [C(4)mim]TFA (1-butyl-3-methyl-imidazolium trifluoroacetic acid), was synthesized and used as an extractant and catalyst for oxidation desulfurization (ODS) of thiophene from model oil with hydrogen peroxide as the oxidant. The major factors of the reaction were investigated in detail. The effect of different types of ILs on oxidative and extractive desulfurization capacities of model oil was tested, which proved TFA(-) > HSO4- > COO- > AlCl4- > AcO-. The reaction heat caused by H2O2 dissolved in IL was determined by a calorimeter.
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