Journal
ENERGY & FUELS
Volume 23, Issue 8, Pages 3859-3865Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ef900273y
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Funding
- Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission
- Ministry of Education, Wuhan, PR China
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A high-performance and environmentally friendly shrimp shell catalyst for biodiesel production was prepared by incomplete carbonization of shrimp shell, loading KF on the resultant, and activation at a desired temperature. The dependence of catalytic activity on preparation conditions Such as carbonization temperature, loading, amount of KF, and activation temperature was investigated. The shrimp shell catalyst was characterized by the Hammett indicator method, thermogravimetric analysis (TGA) and differential thermal analysis (DTA). scanning electron microscope (SEM), N-2 adsorption-desorption, X-ray diffraction (XRD), energy dispersive spectrometer (EDS). element analyzer, and Fourier transform infrared spectrometer (FT-IR). The catalytic performance was evaluated by the transesterification of rapeseed oil with Methanol. The results indicated that the optimum preparation conditions were carbonization at 450 degrees C. loading KF of 25 wt %. and activation at 250 degrees C. The conversion reached 89.1%, using the shrimp shell catalyst when the reaction was carried out at 65 degrees C with a catalyst amount 2.5 wt %. a methanol/rapeseed oil molar ratio 9: 1, and a reaction time of 3 h. The shrimp shell catalyst possesses it porous framework structure, and its catalytic activity for the transesterification came from the active sites formed by the reaction of incompletely carbonized shrimp shell with KF during the activation process. It was found that the shrimp shell catalyst shows high catalytic activity and ecologically friendly properties, having the potential opportunity to be used in biodiesel production process as heterogeneous base catalyst.
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