4.8 Article

Rechargeable Li/CO2-O2 (2:1) battery and Li/CO2 battery

Journal

ENERGY & ENVIRONMENTAL SCIENCE
Volume 7, Issue 2, Pages 677-681

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ee43318h

Keywords

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Funding

  1. CAS [KJCX2-YW-W26]
  2. Chinese Academy of Sciences [XDA01020304]
  3. National project 973 [2012CB932900]

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A Li/CO2-O-2 (2: 1, volume ratio) battery and a Li/CO2 battery with discharging specific capacities of 1808 mA h g(-1) and 1032 mA h g(-1), respectively, are reported. Li2CO3 is the main discharge product in the Li/CO2-O-2 (2 : 1) battery and can be decomposed during charging. In the Li/CO2 battery, the main discharge products could be Li2CO3 and carbon. Both batteries can be cycled reversibly at room temperature.

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