4.8 Article

N-doped graphitic self-encapsulation for high performance silicon anodes in lithium-ion batteries

Journal

ENERGY & ENVIRONMENTAL SCIENCE
Volume 7, Issue 2, Pages 621-626

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ee43322f

Keywords

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Funding

  1. Institute for Basic Science (IBS) [CA1301-2]
  2. Converging Research Program through the Korea government (MEST) [2012K001260]
  3. National Research Foundation of Korea (NRF) [NRF-2012-R1A2A1A01011970]
  4. National Research Foundation of Korea [2012R1A2A1A01011970, 10Z20130011056, 2010-50184] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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N-doped sites at CNT and graphene trigger spontaneous encapsulation of Si particles by simple pH control at room temperature. Significantly, N-doped CNT encapsulated Si composite electrode materials show remarkable cycle life and rate performance in battery operations. Superior capacity retention of 79.4% is obtained after 200 cycles and excellent rate capability of 914 mA h g(-1) is observed at a 10 C rate.

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