Journal
ENERGY & ENVIRONMENTAL SCIENCE
Volume 7, Issue 2, Pages 667-671Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ee43143f
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Funding
- United States Department of Energy, Energy Efficiency and Renewable Energy, Hydrogen and Fuel Cell Program
- Research Foundation Flanders (FWO - Vlaanderen)
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A series of solid magnesium electrolytes were synthesized via the transmetallation of magnesium phenolates to coordinatively unsaturated metal sites lining the pores of the metal-organic frameworks Mg-2(2,5-dioxidobenzene-1,4-dicarboxylate) and Mg-2(4,4'-dioxidobiphenyl-3,3'-dicarboxylate). The resulting materials represent a new class of solid magnesium electrolytes that are both crystalline, and exhibit room-temperature ionic conductivities up to 0.25 mS cm(-1). The materials reported herein are one-hundred times more conductive at room temperature than any other solid magnesium electrolyte and represent the only class of materials sufficiently conductive for practical consideration in magnesium batteries.
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