Journal
ENERGY & ENVIRONMENTAL SCIENCE
Volume 7, Issue 5, Pages 1653-1656Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ee00442f
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Funding
- Grace Ordaz (US-DOE)
- Center for Integrated Nanotechnologies
- DOE Nanoscience User Facility (DLS instrumentation)
- DOE office of EERE (Energy Efficiency and Renewable Energy) [NA25396, DE-EE-0005658]
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In contrast to neat ammonia-borane (AB), the thermal decomposition of AB with N-substituted amine-boranes yields a liquid product after extended heating and H-2 release. NMR and GPC data indicate that co-oligomerization has occurred. These results show promise for developing high energy density AB-based fuel formulations for automotive applications.
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