4.8 Article

TiO2 nanodisks designed for Li-ion batteries: a novel strategy for obtaining an ultrathin and high surface area anode material at the ice interface

Journal

ENERGY & ENVIRONMENTAL SCIENCE
Volume 6, Issue 10, Pages 2932-2938

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ee41880d

Keywords

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Funding

  1. Global Frontier R&D Program on Center for Multiscale Energy System
  2. NRF under the Ministry of Science, ICT Future, Korea [2011-0031571]
  3. KOSEF EPB center [2008-0061892]
  4. KCAP (Sogang Univ.) [2012M1A2A2671779]
  5. Mid-career research program by MEST through the NRF [2012R1A2A2A01002879]
  6. National Research Foundation of Korea [2008-0061892, 2011-0031571, 2009-0093880] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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A rapid and relatively large-scale production of ultrathin TiO2 nanodisks was achieved under mild conditions by developing a novel and simple sol-gel process occurring at the interface of an organic solvent and ice. Owing to the ultrathin structure and unusually high surface area (>400 m(2) g(-1)), the TiO2 nanodisks exhibited high reversible capacity (191.4 mA h g(-1) at 0.2 C) and excellent rate performance (58% capacity retention at 20 C) as an anode in lithium ion batteries.

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