Journal
ENERGY & ENVIRONMENTAL SCIENCE
Volume 6, Issue 8, Pages 2460-2464Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3ee00043e
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Funding
- UK's Engineering & Physical Sciences Research Council [EP/G00434X/2]
- EPSRC [EP/G00434X/2, EP/G00434X/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/G00434X/2, EP/G00434X/1] Funding Source: researchfish
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Electrochemical quartz crystal microbalance measurements with energy dissipation monitoring (E-QCM-D) show that the catalytic lifetime of the O-2-reducing multicopper oxidase bilirubin oxidase from Myrothecium verrucaria, adsorbed on or covalently attached to a organothiol-modified gold electrode, is shortened from days to hours when the applied potential is cycled to below a critical potential (0.6 V vs. SHE at pH 6.0)
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