Journal
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
Volume 19, Issue 1-3, Pages 150-153Publisher
WORLD SCI PUBL CO INC
DOI: 10.1142/S1088424614500990
Keywords
corrole; tungsten; early transition metal; air sensitive
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Funding
- UC-MEXUS Fellowship
- International Fulbright Science and Technology Fellowship
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The first example of a tungsten(V) corrole complex, (Mes(2)(p-OMePh)corrole)WCl2, has been prepared through a metathesis reaction of a lithium corrole (Mes(2)(p-OMePh)corrole)Li-3 center dot 6THF and WCl6. The product constitutes the first example of a tungsten(V) corrole complex synthesized under mild conditions and only the second example of a tungsten corrole complex.
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