4.8 Article

First implementation of alkaline polymer electrolyte water electrolysis working only with pure water

Journal

ENERGY & ENVIRONMENTAL SCIENCE
Volume 5, Issue 7, Pages 7869-7871

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2ee22146b

Keywords

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Funding

  1. National Basic Research Program [2012CB932800, 2012CB215500]
  2. National Science Foundation of China [20933004, 21125312]
  3. National Hi-Tech RD Program [2011AA050705]
  4. Program for Changjiang Scholars and Innovative Research Team in University [IRT1030]
  5. Doctoral Fund of Ministry of Education of China [20110141130002]
  6. Fundamental Research Funds for the Central Universities [203275662, 203275672]

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A new type of water electrolysis is implemented using an alkaline polymer electrolyte (APE) and non-precious metal catalysts, and working only with pure water. The membrane-electrode assembly (MEA) is fabricated by sandwiching a self-crosslinking quaternary ammonia polysulfone (xQAPS) membrane between a Ni-Fe anode and a Ni-Mo cathode, both impregnated with xQAPS ionomer. Such an initial prototype of APE water electrolysis has exhibited decent performance comparable to that of the well-developed alkaline water electrolyzer.

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