4.8 Article

Continuous carbide-derived carbon films with high volumetric capacitance

Journal

ENERGY & ENVIRONMENTAL SCIENCE
Volume 4, Issue 1, Pages 135-138

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ee00404a

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Funding

  1. US Department of Energy, Office of Basic Energy Sciences, Division of Materials Sciences and Engineering [ER46473]
  2. NSF [DMR-0503711]
  3. Partnership University Fund (PUF)

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Monolithic porous carbon film has a great potential for integrated supercapacitors due to no polymer binder, reduced macropore volume, and good adhesion between current collector and active material. It is demonstrated that continuous carbide-derived carbon (CDC) films can be synthesized on various substrates by dry etching. CDC films show high volumetric capacitance of similar to 180 F cm(-3) in 1.5 M TEABF(4)/acetonitrile electrolyte.

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