Journal
ENERGY & ENVIRONMENTAL SCIENCE
Volume 4, Issue 9, Pages 3573-3583Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1ee01488a
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Funding
- National Science Foundation (NSF) Powering the Planet Center for Chemical Innovation (CCI) [CHE-0802907, CHE-0947829]
- Molecular Materials Research Center of the Beckman Institute at the California Institute of Technology
- Department of Energy, Office of Science
- Kavli Nanoscience Institute
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0802907] Funding Source: National Science Foundation
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The dark electrocatalytic and light photocathodic hydrogen evolution properties of Ni, Ni-Mo alloys, and Pt on Si electrodes have been measured, to assess the viability of earth-abundant electrocatalysts for integrated, semiconductor coupled fuel formation. In the dark, the activities of these catalysts deposited on degenerately doped p(+)-Si electrodes increased in the order Ni < Ni-Mo <= Pt. Ni-Mo deposited on degenerately doped Si microwires exhibited activity that was very similar to that of Pt deposited by metal evaporation on planar Si electrodes. Under 100 mW cm(-2) of Air Mass 1.5 solar simulation, the energy conversion efficiencies of p-type Si/catalyst photoelectrodes ranged from 0.2-1%, and increased in the order Ni approximate to Ni-Mo < Pt, due to somewhat lower photovoltages and photocurrents for p-Si/Ni-Mo relative to p-Si/Ni and p-Si/Pt photoelectrodes. Deposition of the catalysts onto microwire arrays resulted in higher apparent catalytic activities and similar photoelectrode efficiencies than were observed on planar p-Si photocathodes, despite lower light absorption by p-Si in the microwire structures.
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