4.8 Article

Structural effects on the surface oxidation processes at Pt single-crystal electrodes studied by X-ray photoelectron spectroscopy

Journal

ENERGY & ENVIRONMENTAL SCIENCE
Volume 4, Issue 5, Pages 1662-1666

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ee00756k

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Funding

  1. Ministry of Education, Science, Culture, Sports, and Technology of Japan [20750007]
  2. New Energy and Industrial Development Organization (NEDO)
  3. Grants-in-Aid for Scientific Research [20750007] Funding Source: KAKEN

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The oxidation states of Pt(111), Pt(100) and Pt(110) in 0.1 M HF solution were analyzed as a function of the electrode potential by EC-XPS. We have, for the first time, clarified the structural effects on the surface oxidation processes at Pt electrodes on the basis of the coverages of each type of oxygen species.

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