Journal
ENERGY & ENVIRONMENTAL SCIENCE
Volume 4, Issue 3, Pages 679-684Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0ee00497a
Keywords
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Funding
- Forschungsgemeinschaft [SFB 583]
- Cluster of Excellence Engineering of Advanced Materials
- European Science Foundation [MAT2006-28170-E]
- MEC of Spain [CT2008-00795/BQU, 2010C-07-25200]
- Comunidad de Madrid [S2009/PPQ-1533]
- MICINN of Spain
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New anionic fullerene-heptamethine conjugates absorbing as far as 900 nm have been synthesized and fully characterized by physicochemical means. In terms of electron transfer, we have succeeded in realizing the rarely occurring scenario of a charge transfer commencing with a higher excited state. Kinetic studies reveal that charge separation and charge recombination dynamics occur in the normal and inverted Marcus region, respectively.
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