4.8 Article

Template-free synthesis of closed-microporous hybrid and its application in quasi-solid-state dye-sensitized solar cells

Journal

ENERGY & ENVIRONMENTAL SCIENCE
Volume 2, Issue 5, Pages 524-528

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b821908g

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Funding

  1. National High Technology Research and Development Program of China [SQ2008AA03Z2470974]
  2. National Natural Science Foundation of China [50572030, 50842027]
  3. Key Project of Chinese Ministry of Education [206074]
  4. Specialized Research Fund for the Doctoral Program of Chinese Higher Education [20060385001]

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A kind of closed-microporous hybrid with poly(acrylic acid)-poly(ethylene glycol)-polypyrrole (PAA-PEG-PPy) was synthesized template-free by in situ polymerization and micro-phase separation of PPy in PAA-PEG gel. This novel structure hybrid was used as a matrix in preparing polymer gel electrolytes for quasi-solid-state dye-sensitized solar cells (QS-DSSC). It shows high liquid electrolyte absorbency and salt tolerance, which are benefits for improving photovoltaic performance of QS-DSSC.

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