Journal
JOURNAL OF POROUS MATERIALS
Volume 22, Issue 3, Pages 629-634Publisher
SPRINGER
DOI: 10.1007/s10934-015-9935-7
Keywords
Carbon materials; Mesoporous; Hollow sphere; Sulfonation
Funding
- program for New Century Excellent Talents in University [NCET-12-0696]
- Leading Talents for Zhengzhou Science and Technology Bureau [131PLJRC649]
- program for University Innovative Talents of Science and Technology in Henan Province [2012HASTIT03]
- National Natural Science Foundation of China [51472102]
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SO3H-functionalized hollow mesoporous carbon sphere (HMCS-SO3H) was successfully synthesized via a facile strategy using inexpensive resins as precursor in combination with metal oxide template. By the one-step thermal treatment with sulfuric acid, it simultaneously achieved the formation of hollow spherical structure and sulfonation functionalization. HMCS-SO3H catalyst possessed superior mesoporosity, uniform sphere morphology and high acidity, which endowed it excellently catalytic property for esterification of oleic acid. In addition, HMCS-SO3H exhibited prominent stability and reusability.
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