4.7 Article

Enhanced high-temperature thermoelectric properties of Ce- and Dy-doped ZnO for power generation

Journal

ENERGY
Volume 54, Issue -, Pages 139-145

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.energy.2013.03.023

Keywords

ZnO; Thermoelectric materials; Sintering; Electrical properties; Ceramics

Funding

  1. Basic Science Research Program through the National Research Foundation of Korea (NRF)
  2. Ministry of Education, Science and Technology [2012R1A1A2009194]
  3. National Research Foundation of Korea [2012R1A1A2009194] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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The incorporation of CeO2 and Dy2O3 to ZnO leads to a marked increase in the electrical conductivity. The absolute values of the Seebeck coefficients of Zn1-xCexO and Zn1-xDyxO increase with CeO2 and Dy2O3 contents up to x = 0.003 and 0.005, respectively, and then decrease with further increases of their concentrations. The highest power factor (4.46 x 10(-4) Wm(-1) K-2 at 800 degrees C) is attained for Zn0.995Dy0.005O. The power factor is approximately 56 times larger than that of ZnO (0.08 x 10(-4) Wm(-1) K (-2) at 800 degrees C). The introduction of a small amount of Dy2O3 is highly effective for improving the thermoelectric properties of ZnO. (C) 2013 Elsevier Ltd. All rights reserved.

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