Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 54, Issue 2, Pages 245-252Publisher
WILEY
DOI: 10.1002/pola.27727
Keywords
block copolymers; functionalization of polymers; inorganic polymers; polysiloxanes; synthesis
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Funding
- EPSRC
- European Research Council
- EU
- EPSRC [EP/K03927X/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [1245296, EP/K03927X/1] Funding Source: researchfish
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A general route for the N-hydroxysuccinimidyl (NHS) ester functionalization of poly(ferrocenyldimethylsilane)-b-polyvinylsiloxane copolymers, which should be readily transferrable to other vinyl containing polymers, has been developed using a simple two step approach. Facile reaction of the NHS ester functionalized polymers with primary amines enables the incorporation of a range of functionalities previously inaccessible using standard thiol-ene click reactions. (C) 2015 Wiley Periodicals, Inc.
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