4.2 Article

Versatile and Controlled Functionalization of Polyferrocenylsilane-b-Polyvinylsiloxane Block Copolymers Using a N-hydroxysuccinimidyl Ester Strategy

Journal

Publisher

WILEY
DOI: 10.1002/pola.27727

Keywords

block copolymers; functionalization of polymers; inorganic polymers; polysiloxanes; synthesis

Funding

  1. EPSRC
  2. European Research Council
  3. EU
  4. EPSRC [EP/K03927X/1] Funding Source: UKRI
  5. Engineering and Physical Sciences Research Council [1245296, EP/K03927X/1] Funding Source: researchfish

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A general route for the N-hydroxysuccinimidyl (NHS) ester functionalization of poly(ferrocenyldimethylsilane)-b-polyvinylsiloxane copolymers, which should be readily transferrable to other vinyl containing polymers, has been developed using a simple two step approach. Facile reaction of the NHS ester functionalized polymers with primary amines enables the incorporation of a range of functionalities previously inaccessible using standard thiol-ene click reactions. (C) 2015 Wiley Periodicals, Inc.

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