4.4 Article

Development of high strength Sn-Mg solder alloys with reasonable ductility

Journal

ELECTRONIC MATERIALS LETTERS
Volume 9, Issue 5, Pages 575-585

Publisher

KOREAN INST METALS MATERIALS
DOI: 10.1007/s13391-013-2168-5

Keywords

Sn-Mg solders; lead-free solder; microstructure; melting temperature; mechanical properties

Funding

  1. Minerals, Metals and Materials Technology Centre (M3TC) of the National University of Singapore [C-534-000-003-414]

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This study discussed the development of a series of new lead-free Sn-Mg solders by incorporating varying amounts of Mg (0.8, 1.5 and 2.5 wt. %) into pure Sn using disintegrated melt deposition technique followed by room temperature extrusion. All extruded Sn and Sn-Mg solder samples were characterized. Microstructural characterization studies revealed equiaxed grain morphology, minimal porosity and relatively uniform distribution of secondary phase. Better coefficient of thermal expansion was observed for Sn-2.5Mg sample when compared to conventional Sn-37Pb solder. Melting temperature of Sn-1.5Mg was found to be 212A degrees C which is much lower than the conventional Sn-Ag-Cu or Sn-Cu (227A degrees C) solders. Microhardness was increased with increasing amount of Mg in pure Sn. Room temperature tensile test results revealed that newly developed Sn-Mg solders exhibit enhanced strengths (0.2% yield strength and ultimate tensile strength) with comparable (if not better) ductility when compared to other commercially available and widely used Sn-based solder alloys.

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