Journal
ELECTROCHIMICA ACTA
Volume 134, Issue -, Pages 67-75Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2014.04.094
Keywords
Activated carbon; Fe2O3; Composite; Solvothermal synthesis; Electrochemical capacitor
Categories
Funding
- China Postdoctoral Science Foundation [2012M520605]
- Qualified Personnel Foundation of Taiyuan University of Technology [tyut-rc201369a]
- National Natural Science Foundation of China (NSFC) [51175363, 51274149]
- Open Foundation of State Key Laboratory of Coal Conversion [09-102]
- Shanxi Provincial Key Innovative Research Team in Science and Technology [2012041011]
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This article describes a facile solvothermal synthesis method to prepare Fe2O3/AC composites for electrochemical capacitors from Iron (III) chloride hexahydrate (FeCl(3 center dot)6H(2)O), activated carbon (AC, from petroleum coke), and four different precipitants (i.e., NaOH, CH3COONa, HMT, CO(NH2)(2)). X-ray powder diffraction (XRD), Scanning electron microscopy (SEM), Energy dispersive spectroscopy (EDS) and Thermogravimetric (TG) analysis show that the products consisted of nanosized alpha-Fe2O3 (weight ratios: 48.1, 47.9, 44.2, 44.3%) loaded onto AC particles (similar to 20 mu m). Significantly, both kind and dosage of precipitants exhibit effects on the specific capacitances of Fe2O3/AC composites. The highest specific capacitance reaches up to 240 F g(-1) (at a current density of 1 A g(-1) in 6 M KOH aqueous electrolyte) when the molar ratio of CH3COONa: FeCl3 is 9. On the other hand, the sample prepared with NaOH: FeCl3 molar ratio being 1.5 exhibits excellent rate capability with specific capacitance of 215 F g(-1) at 1 A g(-1), and 89.3, 82.3, 78.1, 72.6 and 65.1% capacity retention at 2, 5, 10, 20, and 40 A g-1, respectively. These electrochemical performances are superior to other materials consisted of Fe2O3/carbon nanotube (CNT), graphene oxide (GO) or reduced graphene oxide (rGO) composites, demonstrating the great potential of Fe2O3/AC composites in the development of high-performance electrode materials for electrochemical capacitors. (C) 2014 Elsevier Ltd. All rights reserved.
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