Journal
ELECTROCHIMICA ACTA
Volume 113, Issue -, Pages 9-16Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2013.09.031
Keywords
Graphene sheets; Cathodic exfoliation; Ionic liquids; Lithium-ion battery; Porous materials
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Funding
- NNSF of China [51134007, 21003161, 21250110060]
- Funds for Distinguished Young Scientists of Hunan Province, China [13111004]
- Fundamental Research Funds for the Central Universities of Central South University [2012zzts059]
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Electrochemically cathodic exfoliation in room temperature ionic liquids N-butyl, methylpyrrolidinium bis(trifluoromethylsulfonyl)-imide (BMPTF2N) has been developed for few-layer graphene sheets, demonstrating low levels of oxygen (2.7 at% of O) with a nearly perfect structure (I-D/I-G < 0.05). The mechanism of cathodic exfoliation in BMPTF2N involves the intercalation of ionic liquids cation [BMP](+) under highly negatively charge followed by graphite expansion. Porous activated graphene sheets were also obtained by activation of graphene sheets in KOH. Transmission electron microscopy, X-ray photoelectron spectroscopy and Raman spectroscopy were used to characterize these graphene materials. The electrochemical performances of the graphene sheets and porous activated graphene sheets for lithiumion battery anode materials were evaluated using cyclic voltammetry, galvanostatic charge-discharge cycling, and electrochemical impedance spectroscopy. (C) 2013 Elsevier Ltd. All rights reserved.
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