Journal
ELECTROCHIMICA ACTA
Volume 94, Issue -, Pages 159-164Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2013.01.087
Keywords
Methanol; Electrochemical oxidation; Electrocatalysis; Nanomaterials; Nanogold catalyst
Categories
Funding
- Natural Science Foundation of Beijing [2051001]
- National Basic Research Program of China [2007CB936502]
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Au nanoparticles (AuNPs) supported on activated carbon (Au/C) were prepared by a modified chemical reduction method. The morphology, structure, surface chemical state and electro-oxidation activity of AuNPs were investigated by the transmission electron microscope (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), cyclic voltammetry (CV) and chronoamperometry. Results indicated that the Au/C catalyst possessed small AuNPs with a certain number of gold oxide species. This intrinsic property resulted in the high catalytic activity of the Au/C catalyst for the electro-oxidation of alcohol molecule. The peak values of anodic mass-specific current densities on AuNPs reached 69.5, 442 and 660 mA mg(-1) Au, respectively in 0.1 M KOH solutions with 6 M methanol, 2 M ethanol and 0.5 M ethylene glycol. (C) 2013 Elsevier Ltd. All rights reserved.
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