Journal
ELECTROCHIMICA ACTA
Volume 95, Issue -, Pages 12-17Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2013.02.004
Keywords
Electrospinning; CeO2/Au composite nanofibers; Electrocatalysis; Dopamine
Categories
Funding
- National Natural Science Foundation of China [51273075, 21274052]
- Jilin Science and Technology Department project [201115014]
- Fok Ying Tung Education Foundation, China
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An electrochemical method for the detection of dopamine based on a glass carbon electrode modified with electrospun CeO2/Au composite nanofibers was investigated in this article. The CeO2/Au composite nanofibers were prepared by the electrospinning technique and then annealed in air. The CeO2/Au composite nanofibers were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) measurements. Cyclic voltammetry (CV) showed that the electrospun CeO2/Au composite nanofibers modified carbon glass electrode exhibited an excellent electrocatalytic response to the dopamine (DA). The detection limit (SIN = 3) was as low as 0.056 mu M and the sensitivity could reach 127 mu A mM(-1) cm(-2). All these demonstrated that the electrospun CeO2/Au composite nanofibers were good electrocatalyst for the oxidation of dopamine. (c) 2013 Elsevier Ltd. All rights reserved.
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