Journal
ELECTROCHIMICA ACTA
Volume 106, Issue -, Pages 460-464Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2013.05.137
Keywords
Flammability; Gel polymer electrolyte; In situ polymerization; Lithium polymer cell; Polymeric ionic liquid
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Funding
- National Research Foundation of Korea
- Korean Government (MEST) [NRF-2009-C1AAA001-0093307]
- Human Resources Development Program of KETEP
- Korea Government Ministry of Trade, Industry and Energy [20124010203290]
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Lithium polymer cells composed of a lithium negative electrode and a LiCoO2 positive electrode were assembled with a gel polymer electrolyte obtained by in situ polymerization of an electrolyte solution containing an ionic liquid monomer with vinyl groups. The polymerization of the electrolyte solution containing the non-flammable ionic liquid monomer resulted in a significant reduction of the flammability of the gel polymer electrolytes. The lithium polymer cell assembled with the stable gel polymer electrolyte delivered a discharge capacity of 134.3 mAh g(-1) at ambient temperature and exhibited good capacity retention. (C) 2013 Elsevier Ltd. All rights reserved.
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