4.6 Article

Zinc oxide-zinc stannate core-shell nanorod arrays for CdS quantum dot sensitized solar cells

Journal

ELECTROCHIMICA ACTA
Volume 68, Issue -, Pages 141-145

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2012.02.036

Keywords

Zinc stannate; Zinc oxide nanorod; Core-shell nanorod; Cadmium sulfide; Quantum dot sensitized solar cell

Funding

  1. Sheikh Saqr Al Qasimi Graduate Research Fellowship
  2. Centre of Excellence in Nanotechnology at the Asian Institute of Technology, Thailand
  3. National Nanotechnology Center (NANOTEC) of National Science & Technology Development Agency (NSTDA), Royal Thai Government

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Nanorod arrays of zinc oxide-zinc stannate core-shell photoelectrodes were prepared by a simple hydrothermal process and cadmium sulfide (CdS) quantum dot sensitized solar cells were fabricated. The photocurrent density of the core-shell photoelectrode was found to improve by 2.4 times compared to ZnO nanorod photoelectrodes, due to improved surface area and charge transport in the core-shell photoelectrodes. With a thin layer of ZnS on the CdS quantum dot surface, the core-shell quantum dot sensitized solar cell demonstrated maximum power conversion efficiency of 1.24% under 1 sun illumination (AM1.5). (C) 2012 Elsevier Ltd. All rights reserved.

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