4.2 Article

Auger electron and photoabsorption spectra of glycine in the vicinity of the oxygen K-edge measured with an X-FEL

Publisher

IOP PUBLISHING LTD
DOI: 10.1088/0953-4075/48/23/234004

Keywords

X-FEL; auger electron; glycine; oxygen; ab initio calculation

Funding

  1. SLAC
  2. Engineering and Physical Sciences Research Council (UK) (EPSRC) [EP/I032517/1]
  3. ERC ASTEX project [290467]
  4. EPSRC [EP/M023729/1]
  5. STFC
  6. Czech Science foundation [P208/12/0521]
  7. x-ray Free Electron Laser Priority Strategy Program of MEXT
  8. Tagen project by IMRAM
  9. Swedish Research Council (V R)
  10. Knut and Alice Wallenberg Foundation, Sweden
  11. Swedish FEL center
  12. US Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-AC02-76SF00515]
  13. EPSRC [EP/I032517/1, EP/M023729/1] Funding Source: UKRI
  14. Engineering and Physical Sciences Research Council [EP/I032517/1, 1227496, 1227506, EP/M023729/1] Funding Source: researchfish

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We report the first measurement of the near oxygen K-edge auger spectrum of the glycine molecule. Our work employed an x-ray free electron laser as the photon source operated with input photon energies tunable between 527 and 547 eV. Complete electron spectra were recorded at each photon energy in the tuning range, revealing resonant and non-resonant auger structures. Finally ab initio theoretical predictions are compared with the measured above the edge auger spectrum and an assignment of auger decay channels is performed.

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