Journal
ELECTROCHIMICA ACTA
Volume 56, Issue 14, Pages 5195-5200Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2011.03.041
Keywords
Additive; N-(triphenylphosphoranylidene) aniline (TPPA); Lithium cobalt oxide (LiCoO2); High voltage operation
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Funding
- Korean Government (MEST) [NRF-2009-0094219, NRF-2010-0029031]
- National Research Foundation of Korea [과C6A1907] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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We report N-(triphenylphosphoranylidene) aniline (TPPA) as a new electrolyte additive for high performance lithium cobalt oxide (LiCoO2) electrodes during high voltage operations. When cycled in the voltage range of 3.0-4.4 V. graphite-LiCoO2 full cells with 0.2 wt%TPPA exhibited 10% increased discharge capacities after 200 cycles compared to those of control cells with no such additive. The enhanced cycling performance is attributed to the additive effect toward the modified surface films on LiCoO2 electrodes that suppress the decomposition of both solvent and salt in the electrolyte. This additive effect was characterized by electrochemical impedance spectroscopy (EIS) and X-ray photoelectron spectroscopy (XPS). (C) 2011 Elsevier Ltd. All rights reserved.
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